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Typical Application Cases of Super Duplex Steel
Sep 19, 2025

In the evolution of materials science, duplex stainless steel, with its unique "austenite + ferrite" dual-phase microstructure, offers both high strength and excellent corrosion resistance, making it an ideal choice for many harsh environments. Super Duplex Stainless Steel, such as 2507 and UR52N+, as high-end products within this family, achieves pitting resistance equivalent values (PREN) exceeding 40 (compared to 30-35 for standard duplex steels) by further increasing chromium, molybdenum, and nitrogen content. This demonstrates irreplaceable advantages in surviving the combined challenges of chloride ion corrosion, stress corrosion, and mechanical wear. This article will focus on three typical application scenarios—deepwater oil and gas platforms, nuclear power cooling systems, and high-end environmental protection equipment—to analyze how super duplex steel addresses engineering challenges through its material properties.

 

Deepwater Oil and Gas Platforms - The "Structural Cornerstone" for Withstanding High-Salt, High-Pressure Environments

Scenario Challenges:

In offshore oil and gas production, subsea pipelines, Christmas trees, and underwater production systems are exposed to long-term environments containing chloride ions (concentrations exceeding 30,000 ppm), low temperatures (0-10°C), and high pressures (20-30 MPa). Ordinary carbon steel or low-alloy steel rapidly fails due to pitting and crevice corrosion induced by chloride ions. While traditional austenitic stainless steels (such as 316L) offer good corrosion resistance, they lack strength (yield strength is typically only 200-300 MPa), making them difficult to meet the lightweighting requirements of deepwater, high-pressure equipment.

Super Duplex Steel Solutions:

Take 2507 super duplex steel, for example. Its yield strength reaches 450-550 MPa (approximately twice that of 316L), allowing it to withstand higher pressures without increasing wall thickness. Crucially, its high chromium (25%), molybdenum (3.5-4%), and nitrogen (0.2-0.3%) content synergistically forms a dense passive film (primarily composed of Cr₂O₃ and MoO₃ derivatives), which stably resists chloride ions attacking the metal grain boundaries.

Practical Application Example:

Equinor, the Norwegian national oil company, uses 2507 super duplex steel to manufacture valve bodies and connecting flanges for underwater production at the Johan Sverdrup oil field in the North Sea. The field's seawater has a chloride ion concentration exceeding 25,000 ppm and winter temperatures near 0°C. Yet, after five years of continuous service, the equipment remains corrosion-free. Meanwhile, auxiliary pipelines made of conventional duplex steel (such as 2205) were replaced prematurely due to localized pitting corrosion. Data shows that under these operating conditions, the pitting corrosion rate of 2507 steel is less than 0.01mm/year (far exceeding the API 17D standard's upper limit of 0.1mm/year), and its resistance to sulfide stress cracking (SSCC) meets NACE MR0175 standards, becoming the "safety baseline" for deepwater equipment.

 

Nuclear Power Cooling System - Meeting High Nuclear Safety and Radiation Resistance Standards

Scenario Challenge:

While the secondary circuit of a nuclear power plant (the circulation system from the steam generator to the steam turbine) does not directly contact radioactive materials, the cooling water contains trace amounts of chloride ions (from feedwater treatment residues) and operates at high temperatures (280-320°C). Traditional materials are susceptible to stress corrosion cracking (SCC) due to long-term operation. More importantly, nuclear-grade equipment places extremely high demands on the material's radiation stability (resistance to neutron embrittlement), weldability, and long-term structural stability. When ordinary duplex steel is used for extended periods above 300°C, brittle σ phases may precipitate from the ferrite phase, reducing toughness. Super Duplex Steel Solution:

UR52N+ (a commonly used super duplex steel in Europe, with a composition similar to 2507 but featuring an optimized distribution of nitrogen and molybdenum) maintains a balanced duplex structure at 300°C through precise control of the phase ratio (austenite:ferrite approximately 50:50, with a deviation of less than 5%), preventing excessive growth of a single phase. Furthermore, its high nickel content (approximately 7%) enhances the matrix's resistance to radiation swelling, while the addition of nitrogen inhibits the precipitation rate of the σ phase at high temperatures.

Practical Application Example:

At the Flamanville Nuclear Power Plant Phase III project in France, the steam generator secondary header (a key component responsible for distributing cooling water) is manufactured using UR52N+. Operating at a temperature of 290°C, the chloride ion concentration in the cooling water is kept below 50 ppm (although still higher than that of conventional industrial water). Since its commissioning in 2018, regular eddy current testing has revealed no wall thinning or crack growth, extending its design life from 20 years for conventional materials to 40 years. An International Atomic Energy Agency (IAEA) assessment report indicates that UR52N+'s comprehensive corrosion resistance under these conditions is more than three times that of standard duplex steels (such as 2205), while the impact toughness of welded joints remains above 80J (far exceeding the nuclear-grade standard requirement of 50J).

 

High-End Environmental Protection Equipment - Wet Flue Gas Desulfurization Systems Require Extremely High Wear and Corrosion Resistance

Scenario Challenge:

In wet flue gas desulfurization (FGD) systems in coal-fired power plants or steel mills, the slurry circulation pump and the inner wall of the absorption tower are exposed to a chlorinated sulfate slurry with a pH of 4-6 (15-30% solids content, Cl⁻ concentration of 5,000-10,000 ppm), accompanied by high-velocity fluid erosion (flow rates of up to 3-5 m/s). Conventional corrosion-resistant materials, such as rubber linings, are easily penetrated by solid particles, while 316L stainless steel, under the combined effects of Cl⁻ and slurry erosion, can develop perforations and leaks within months.

Super Duplex Steel Solution:

2507 Super Duplex Steel not only offers high corrosion resistance, but also boasts a significantly higher hardness (HV 280-320) than 316L (HV 180-220), effectively resisting cutting wear from solid particles. Furthermore, the ferrite phase in the duplex structure provides enhanced resistance to plastic deformation, while the austenite phase buffers impact stresses. These two phases combine to achieve dual corrosion and wear resistance.

Application Example:

In the captive power plant of a large steel mill under China Baosteel Group, the impeller of the FGD slurry circulation pump was originally constructed from 316L stainless steel, experiencing an average service life of only eight months (due to wear leading to impeller imbalance and eventual fracture). The impeller was subsequently replaced with a single-piece cast 2507 Super Duplex Steel impeller, combined with an optimized flow channel design. After 26 months of continuous operation under the same operating conditions, only minor surface scratches (wear depth <0.3mm) were observed. After repair, the impeller continued to operate, extending the replacement cycle to over three years and reducing overall maintenance costs by 60%.

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